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Diffuse Double Layer
At the electrode-electrolyte interface, there is a thin layer of space charge in a diffuse double layer. This may be of interest when modeling devices such as electrochemical capacitors and nanoelectrodes. This tutorial example shows how to couple the Nernst-Planck equations to the ... Читать дальше
Electrochemical Impedance Spectroscopy
Electrochemical impedance spectroscopy (EIS) is a common technique in electroanalysis. It is used to study the harmonic response of an electrochemical system. A small, sinusoidal variation is applied to the potential at the working electrode, and the resulting current is analyzed in the ... Читать дальше
Cyclic Voltammetry at a Macroelectrode in 1D
Cyclic voltammetry is a common analytical technique for investigating electrochemical systems. In this method, the potential difference between a working electrode and a reference electrode is swept linearly in time from a start potential to a vertex potential, and back again. The ... Читать дальше
Localized Corrosion
Galvanic corrosion between two different phases (alpha and beta phases) in a metallic (magnesium) alloy is simulated for a representative cross-sectional microstructure configuration. A key feature in the model formulation is the implementation of both anodic and cathodic regions at ... Читать дальше
Stress Corrosion
Steel pipelines are often subjected to complex stress/strain conditions in the oil and gas industry. Additionally, pipes are subjected to significant longitudinal strain due to soil movement. For the elastoplastic stress simulation, the _Solid Mechanics_ interface is used with the small ... Читать дальше
Orange Battery
This tutorial example models the currents and the concentration of dissolved metal ions in a battery (corrosion cell) made from an orange and two metal nails. This type of battery is commonly used in chemistry lessons. Instead of an orange, lemons or potatoes can also be used. Читать дальше
Corrosion Protection of a Ship Hull
Impressed current cathodic protection is a commonly employed strategy to mitigate the ship hull corrosion where an external current is applied to the hull surface, polarizing it to a lower potential. In this model, the effect of propeller coating on the current demand is demonstrated. Читать дальше
Carbon Dioxide Corrosion in Steel Pipes
Carbon dioxide in aqueous solution is highly corrosive and can cause significant damage to steel designs. Such conditions arise in pipes used in a variety of applications, especially within the petrochemical industry. In this tutorial example, turbulent flows consisting of carbon ... Читать дальше
Under-Deposit Corrosion
In this model, the effect of corrosion product on galvanic corrosion between a magnesium alloy (AE44) and mild steel in contact with brine solution is presented, wherein deformed boundaries due to both deposition of corrosion product as well as dissolution of magnesium are considered. ... Читать дальше
Voltammetry at a Microdisk Electrode
Voltammetry is modeled at a microelectrode of 10um radius. In this common analytical electrochemistry technique, the potential at a working electrode is swept up and down and the current is recorded. The current-voltage waveform ("voltammogram") gives information about the reactivity and ... Читать дальше